We consider the thermodynamic stability conditions (TSC) on the Boltzmann entropies generalized by Tsallis' q-and Kaniadakis' Γ-deformed logarithmic functions. It is shown that the corresponding TSCs are not necessarily equivalent to the concavity of the generalized Boltzmann entropies with respect
Thermodynamical entropy (and its additivity) within generalized thermodynamics
β Scribed by M.P. Almeida
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 158 KB
- Volume
- 325
- Category
- Article
- ISSN
- 0378-4371
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β¦ Synopsis
This is an analysis of the thermodynamical entropy of systems with ΓΏnite heat baths and of its additivity. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown how it relates to the traditional entropies of the micro-canonical (constant energy), the canonical Boltzmann-Gibbs (inΓΏnite heat bath) and the Tsallis (ΓΏnite heat bath) ensembles. This physical entropy contains one term that is a variant of the Tsallis entropy, and it becomes an additive function after a suitable choice of additive constants, in a procedure reminiscent to the solution presented by Gibbs to the paradox bearing his name.
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