𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermodynamic vs. kinetic control in the Diels-Alder cycloaddition of cyclopentadiene to 2,3-dicyano-p-benzoquinone

✍ Scribed by Simon G. Bott; Alan P. Marchand; Kaipenchery A. Kumar


Book ID
105275220
Publisher
Springer
Year
1996
Tongue
English
Weight
367 KB
Volume
26
Category
Article
ISSN
1572-8854

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Thermodynamic vs. kinetic control in the
✍ Alan P. Marchand; Bishwajit Ganguly; William H. Watson; Satish G. Bodige πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 318 KB

Diels-Alder cycloaddition of cyclopentadiene (1) to 2,3-dicyano-p-benzoquinone (2), when performed in methanol solvent at ambient temperature (kinetic control), gave 3b. Reduction of 3b, carried out under mild conditions by using CeCI3-NaBH4, proceeded stereospecifically to afford diol $. Subsequent

Thermodynamic vs. kinetic control in the
✍ Roberta Galeazzi; Giovanna Mobbili; Mario Orena πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 825 KB

Intramolecular conjugate addition of amide enolates to ct,l~-unsaturated esters was found to give either of the diastereomeric trans-3,4-disubstituted pyrrolidin-2-ones 6, 10 or 7, 11 as the major products, by choosing the appropriate reaction conditions. The cyclisation performed with Nail in THF a