Thermodynamic trans-Effects of the Nucleotide Base in the B12 Coenzymes

✍ Scribed by Bernhard Kräutler

• Book ID: 102859278
• Publisher: John Wiley and Sons
• Year: 1987
• Tongue: German
• Weight: 718 KB
• Volume: 70
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19870700506

✦ Synopsis

Besides their roles as organometallic catalysts, BIZ derivatives have recently been proposed to function as electron-transfer agents also in methanogenic bacteria [ S ] . The Co-C bond homolysis energy of I has been determined in two laboratories [6] by kinetic methods to amount to ca. 30 kcd/mol (for aqueous solutions of 1).