Thermodynamic studies on A2U4O12 and A2U4O13 (A = CsRb) system by emf and calorimetric measurements at high temperatures

Thermodynamic Properties of K2U4O12(s) a

Thermodynamic Properties of K2U4O12(s) and K2U4O13(s) by EMF and Calorimetric Measurements

✍ V.S. Iyer; K. Jayanthi; V. Venugopal 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 267 KB

The coexistence of K 2 U 4 O 12 (s) and K 2 U 4 O 13 (s) in the K-U-O system up to 1200 K was established. The EMF measurements over the above phase field were carried out using a calciastabilized zirconia solid electrolyte galvanic cell in the temperature range 1053 to 1222 K. The equilibrium oxyge