Thermodynamic secondary deuterium isotope effect in the thermal rearrangement of biallyl
✍ Scribed by R. Malojčić; K. Humski; S. Borčić; D.E. Sunko
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 140 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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## Abstract Reaction rates for the protodesilylation of trimethylphenylsilane and of [2,4,6‐^2^H~3~]‐trimethylphenylsilane by HCIO~4~, were measured in aqueous methanol (2:5, __v/v__) and the secondary deuterium isotope effect for the reaction was found to be __k__~H~/__k__~D3~ = 0.79. The magnitud