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Thermodynamic properties of silicides. III. Specific energy of combustion in fluorine of a hyperstoichiometric molybdenum disilicide. The standard molar enthalpy of formation ΔfHom of MoSi2.067±0.002 at the temperature 298.15 K

✍ Scribed by P.A.G. O'Hare

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
369 KB
Volume
25
Category
Article
ISSN
0021-9614

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The massic energy of combustion of vanadium disilicide in fluorine according to the reaction VSi 2 (cr) + (13/2)F 2 (g) = VF 5 (g) + 2SiF 4 (g) has been measured calorimetrically. On the basis of the derived molar enthalpy of reaction and the standard molar enthalpies of formation f H o m of VF 5 (g

Thermodynamic properties of silicides: I
Thermodynamic properties of silicides: IV. Determination of the standard molar enthalpies of formation at the temperature 298.15 K of pentatungsten trisilicides of composition W5Si3and W5Si3.115by fluorine-combustion calorimetry
✍ Iwona Tomaszkiewicz; G.A. Hope; Charles M. Beck; II; P.A.G. O’Hare 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 429 KB

Two fully characterized specimens of pentatungsten trisilicide, nominally W5Si3, one believed to have been prepared by direct reaction of the elements in a sealed tube, and the other by arc melting, have been studied by fluorine-combustion calorimetry. Chemical analyses of the samples played a pivot