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Thermodynamic properties of pyridine—II. Comparisons of new recommended values with the literature

✍ Scribed by R.D. Chirico; W.V. Steele

Book ID
102968880
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
600 KB
Volume
28
Category
Article
ISSN
0021-9614

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✦ Synopsis

Thermodynamic properties of pyridine (Chemical Abstracts registry number 110-86-1) are reviewed, and detailed comparisons between literature values and new recommended values of this research are provided. Properties reviewed are condensed-and gas-phase molar heat capacities, the molar enthalpy of combustion, vapor pressures, densities, critical properties, virial coefficients, molar enthalpies of vaporization, and molar thermodynamic properties derived from assigned vibrational spectra. In a companion paper to this review, new vapor pressures, high-temperature molar heat capacities, and densities are reported which show that previously assessed values for pyridine require revision. Recommendations are made for values of all properties reviewed. Thermodynamic consistency between properties is emphasized.

📜 SIMILAR VOLUMES

Thermodynamic properties of pyridine—I.
Thermodynamic properties of pyridine—I. Vapor pressures, high-temperature heat capacities, densities, critical properties, derived thermodynamic functions, vibrational assignment, and derivation of recommended values
✍ R.D. Chirico; W.V. Steele; A. Nguyen; T.D. Klots; S.E. Knipmeyer 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 592 KB

Measurements leading to the calculation of standard thermodynamic properties for pyridine (Chemical Abstracts registry number 110-86-1) are reported for temperatures from the triple-point temperature Ttp=231.51 K to T=560 K. The standard state is defined as the ideal gas at the pressure p=p°=101.325