Thermodynamic properties of holmium silicides HoSi1−x, Ho5Si4, AND Ho5Si3
✍ Scribed by L. V. Goncharuk; V. R. Sidorko; Yu. I. Buyanov
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 202 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1573-9066
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Two fully characterized specimens of pentatungsten trisilicide, nominally W5Si3, one believed to have been prepared by direct reaction of the elements in a sealed tube, and the other by arc melting, have been studied by fluorine-combustion calorimetry. Chemical analyses of the samples played a pivot
After melting and quenching, the ternary silicides \(\mathrm{U}_{2} \mathrm{Fe}_{11-y} \mathrm{Si}_{y}\) exist for \(3.3 \leq y \leq 4.5\) but they partially decompose after annealing at \(850-900^{\circ} \mathrm{C}\). Their crystal structure, determined by \(\mathrm{X}\)-ray diffractometry on both