Thermodynamic properties of donor–acceptor complexes of tertiary amine with aryl ketones in hexane medium

n—π electron-donor—acceptor complexes—IV

n—π electron-donor—acceptor complexes—IV. The interaction of aliphatic amines with 1,3-dicyanobenzene in n-hexane. The importance of preferred orientation in the stability of the complexes

✍ M.A. Biasutti; J.D. Anunziata; J.J. Silber 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 381 KB

Abstmct-The stability constants (K) for the electron-donor-acceptor (EDA) complexes formed between aliphatic amines as n-donors and 1,3\_dicyanobenxene (1,3-DCB) have been determined in n-hexane as solvent. By means of free energy substitutent parameters and regression analysis, the electronic and s