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Thermodynamic properties of binary mixtures of I-hexyne and polar organic solvents

✍ Scribed by H. G. Harris; J. M. Prausnitz

Publisher: American Institute of Chemical Engineers
Year: 1968
Tongue: English
Weight: 390 KB
Volume: 14
Category: Article
ISSN: 0001-1541
DOI: 10.1002/aic.690140511

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✦ Synopsis

Vapor-liquid equilibrium data for polar solvent-hydrocarbon mixtures are relatively plentiful for paraffins and aromatics; they are somewhat less plentiful for olefins. However, almost no data a t all have been published for such mixtures wherein the hydrocarbon possesses a triple bond. This paper reports vapor-pressure measurements of binary mixtures of I-hexyne with acetone, acetonitrile, dimethyl carbonate, nitroethane and dimethyl formamide in the temperature range 0 to 70°C. The results are compared with those for polar solvent-hydrocarbon mixtures wherein the hydrocarbon is paraffinic, olefinic, or aromatic.

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