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Thermodynamic Modeling of the Ti-Al-N System and Application to the Simulation of CVD Processes of the (Ti,Al)N Metastable Phase

✍ Scribed by Stéphanie Anderbouhr; Sandra Gilles; Elisabeth Blanquet; Claude Bernard; Roland Madar


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
528 KB
Volume
5
Category
Article
ISSN
0948-1907

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Synthesis and Structure of New Perovskit
✍ P.R. Slater; J.T.S. Irvine 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 94 KB

In this paper we report the synthesis of a new phase in the La+Ti+Al+O system. A starting composition La 2 TiAlO 6.5 and synthesis conditions of 14003C under H 2 /Ar (5%/95%) resulted in a perovskite with a monoclinic (I 2/a; a ‫؍‬ 7.686, b ‫؍‬ 5.435, c ‫؍‬ 5.424 A s , ‫؍‬ 90.203) cell. Although it