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Thermodynamic functions for 2-chloro-and 2-bromopropionitrile

✍ Scribed by A.Y. Cheung; M. Veljkovic; H. Aleman; J. Lielmezs


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
182 KB
Volume
12
Category
Article
ISSN
0040-6031

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Kinetic and thermodynamic study of 2-bro
✍ LΓ­dia C. Albuquerque; Luisa C. Moita; Ana N. SimΓ΅es; Raquel C. GonΓ§alves; EugΓ©ni πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 91 KB πŸ‘ 1 views

Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info