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Thermodynamic control of amination of cyclotriphosphazenes in acetonitrile

✍ Scribed by J.M.E Goldschmidt; M Segev

Publisher
Elsevier Science
Year
1973
Weight
76 KB
Volume
9
Category
Article
ISSN
0020-1650

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The kinetics of the reactions of primary and secondary amines with benzhydrylium ions and quinone methides in acetonitrile have been studied under pseudo-first-order conditions (high excess of amines) by UV/Vis spectrophotometry. Generally, the plots of k obs versus amine concentration were linear,