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Thermodynamic characteristics of excited electronic states

✍ Scribed by Anatoly Kulbida

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 535 KB
Volume: 171
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)80054-h

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✦ Synopsis

It is shown that if the absorption and luminescence spectra are normalized to the integrals of tJu and IJu3, respectively, the intersection point will generally correspond to the difference of the free energy of the system in the ground and in the excited states. Knowing the free-energy difference, one can find the change in other thermodynamic characteristics of the system due to electronic excitation.

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