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Thermodynamic and structural properties of binary mixtures of some glycols with 2-butoxyethanol at T = (293.15, 298.15 and 303.15) K

✍ Scribed by Cezary M. Kinart; Magdalena Klimczak

Publisher: Elsevier Science
Year: 2009
Tongue: English
Weight: 375 KB
Volume: 148
Category: Article
ISSN: 0167-7322
DOI: 10.1016/j.molliq.2009.07.009

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✦ Synopsis

Densities and relative permittivities at T = (293.15, 298.15, and 303.15) K in the binary mixtures of 2butoxyethanol with ethylene glycol, diethylene glycol, triethylene glycol and tetraethylene glycol have been measured as a function of composition. From the experimental data excess molar volumes and deviations in relative permittivity have been calculated over the entire composition range. Both excess molar volumes and relative permittivity deviations have been correlated using Redlich-Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors. The experimental and calculated quantities were used to analyze the mixing behaviour of the components.

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Thermodynamic and structural properties of binary mixtures of some glycols with 2-butoxyethanol at T&#xa0;=&#xa0;(293.15, 298.15 and 303.15) K

✦ Synopsis

Thermodynamic and structural properties of binary mixtures of some glycols with 2-butoxyethanol at T = (293.15, 298.15 and 303.15) K