Thermodynamic and NMR studies of mixed-ligand complex formation of cadmium ethylenediaminetetraacetate with diamines in an aqueous solution
โ Scribed by Pyreu Dmitrii; Kozlovskii Eugenii; Gruzdev Matvei; Kumeev Roman
- Publisher
- Springer Netherlands
- Year
- 2010
- Tongue
- English
- Weight
- 299 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0022-5215
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Standard thermodynamic parameters G, H and S for several series of coordination reactions between mixed ligand complexes of Cd(II) and single entering groups in aqueous solution at T = 298.15 K and constant ionic strength ยต = 1 for KNO 3 were inspected for the occurrence of enthalpy-entropy and free
Dimer formation of poly(L-lysine HBr) in carbonate buffer a t pD 10.5 was reported in our previous paper [Biopolymers (1981) 20,345-3571. The mechanism of the dimer formation was investigated employing carbon-13 and proton nmr. pD dependence of the 13CC-nmr spectrum of poly(L-lysine HBr) in the pres