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Thermodynamic and Conformational Changes upon Stretching a Poly(dimethylsiloxane) Chain in the Melt

✍ Scribed by Smith, James S.; Bedrov, Dmitry; Smith, Grant D.; Kober, Edward M.


Book ID
126062228
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
222 KB
Volume
38
Category
Article
ISSN
0024-9297

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## Abstract The crystallization of bimodal PDMS molecular‐weight blends consisting of long (115 kda) and short (5.3 kda) chains is investigated using DSC and proton NMR. In agreement with earlier studies, it is found that the pure long‐chain sample crystallizes more rapidly than the short‐chain sam