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Thermochromism and photochromism of aryl-substituted acyclic azines III: Investigations on the mechanism of photochemical isomerization

✍ Scribed by K. Appenroth; M. Reichenbächer; R. Paetzold


Publisher
Elsevier Science
Year
1980
Weight
694 KB
Volume
14
Category
Article
ISSN
0047-2670

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The ratios of nucleophilic substitution versus [3,3] sigmatropic rearrangement for the collapse of allenyl(aryl)iodine(III), generated from the reaction of aryliodanes with propargylsilanes in the presence of BF3-Et20 in alcohols, were determined. A proposed mechanism involves generation of propargy