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Thermochemistry of Uracils. Experimental and Computational Enthalpies of Formation of 5,6-Dimethyl-, 1,3,5-Trimethyl-, and 1,3,5,6-Tetramethyluracils

✍ Scribed by Notario, Rafael; Emel'yanenko, Vladimir N.; Roux, María Victoria; Ros, Francisco; Verevkin, Sergey P.; Chickos, James S.; Liebman, Joel F.


Book ID
119940776
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
505 KB
Volume
117
Category
Article
ISSN
1089-5639

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The standard ( p o = 0.1 MPa) molar enthalpies of combustion in oxygen, at T = 298.15 K, for crystalline 3,5-dimethylpyrazole (Me 2 Pyr), 3,5-dimethyl-4-nitrosopyrazole (Me 2 PyrNO), 1,3,5-trimethyl-4-nitrosopyrazole (Me 3 PyrNO), and 3,5-dimethyl-1phenyl-4-nitrosopyrazole (Me 2 PhPyrNO) were measur