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Thermochemistry of the reaction of hydrogen sulfide with iodine and the heat of formation of HSI - a new sulfur compound

✍ Scribed by Hwang, R. J.; Benson, S. W.

Book ID
124062881
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
352 KB
Volume
101
Category
Article
ISSN
0002-7863

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Kinetics of iodination of hydrogen sulfi
Kinetics of iodination of hydrogen sulfide by iodine and the heat of formation of the SH radical
✍ R. J. Hwang; S. W. Benson πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 186 KB πŸ‘ 1 views

The kinetics of the gas-phase thermal iodination of hydrogen sulfide by 12 to yield HSI and HI has been investigated in the temperature range 555-595 K. The reaction was found to proceed through an I atom and radical chain mechanism. Analysis of the kinetic data yields log k (l/mol-sec) = (11.1 f 0.