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Thermochemistry of perthiyl radicals

✍ Scribed by Hawari, J. A.; Griller, D.; Lossing, F. P.


Book ID
127200522
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
411 KB
Volume
108
Category
Article
ISSN
0002-7863

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A new estimate is derived for the group additivity contribution AH,"IO-(O),l = 55 2 6 kJ mol ', based upon recent experimental data, which enables heats of formation and bond dissociation energies to be estimated for species RO,,R and RO, (R = H, CH,, and CF,). Semi-empirical MNDO calculated heats o