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Thermochemistry of organic, elementorganic and inorganic species. Part XX. Enthalpies of formation for free radicals of main group elements’ halogenides

✍ Scribed by Dmitry Ponomarev; Viatcheslav Takhistov; Suzanne Slayden; Joel Liebman


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
392 KB
Volume
876
Category
Article
ISSN
0022-2860

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Systematization of known experimental and theoretical data on the enthalpies of formation for halogenides of main group elements has been performed. Applying the enthalpic shift procedure, the definite trends in the enthalpy of formation/structure interrelationships have been found and these are int

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✍ A.V. Golovin; V.V. Takhistov 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 354 KB

Using IR frequencies for gaseous molecules' R-H bonds, some known values of the enthalpies of formation for carbon-centered R % free radicals, and the series of isodesmic reactions, the enthalpies of formation for more than 25 free radicals were found. The variable Dn CH values equivalent for 1 kcal