Thermochemistry of fullerene anions in the gas phase
โ Scribed by Olga V. Boltalina; Dmitry B. Ponomarev; Lev N. Sidorov
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 190 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0277-7037
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โฆ Synopsis
MSR
*As far as terminology is concerned , the term ''fullerene and high-pressure mass spectrometry (which provide inanion'' is equivalent to ''radical fullerene anion'' here, because we formation on the reactivity of the ions via observations of mainly consider the anions of fullerenes, which are formed by a single electron attachment, unless otherwise indicated. direct interactions with the gaseous reagents) have not
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KEYWORDS : gas phase acidities of 1,2-butadiene and 2-butyne ; heats of formation of anions ; ab initio calculations ; C 4 H 5 Fourier transform ion cyclotron resonance ; gas-phase ion/molecule reactions.
Gas-phase reactions of benzyl and methoxide anions with alkyl formate and other esters were compared using Fourier transform io cyclotron resonance spectroscopy. Although these anions have similar basicities, in many cases the reaction pathways differ.
A(AGI: 4 f l kcal.mol.' Scheme 1. Stability sequence ofcations (1) to (6); D(R@ X"') values taken from l3bl.