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Thermochemistry of ethyl acetate solvation in the 1-octanol-N,N-dimethylformamide system

✍ Scribed by A. V. Kustov; N. L. Smirnova; D. B. Berezin; M. B. Berezin

Book ID
110185546
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2011
Tongue
English
Weight
191 KB
Volume
85
Category
Article
ISSN
0036-0244

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The thermal decomposition rate constant of AIBN ( k d ) in N,N-dimethylformamide (DMF)/ acrylonitrile (AN) mixtures of various compositions at 60Β°C is studied. The k d value is (6.45 +. 0.3) X min-' for pure acrylonitrile. The k d values of DMF/AN mixtures were found to be dependent on the mixture