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Thermochemistry of Complexation of 15-Crown-5 and 18-Crown-6 with Na+and NH+4Ions in Aqueous Solutions

โœ Scribed by V. P. Vasil'ev; M. N. Goncharova; T. V. Balashova; T. D. Orlova; V. V. Chernikov


Book ID
110300856
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
31 KB
Volume
27
Category
Article
ISSN
1070-3284

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Complexes of Lanthanoid Nitrates with 15
โœ Jean-Claude G. Bรผnzli; Denis Wessner ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 860 KB

Complexes between the heavier lanthanoid nitrates Ln(NO~3~)~3~ and 15โ€crownโ€5 (**1**) and 18โ€crownโ€6 (**2**) ethers were isolated and characterized. Both 1:1 and 4:3 complexes are formed with each Ln(III) ion, except in the case of Gd and **2**. The thermal transformation of the 1:1 complexes into t