Thermochemical study of mixed-ligand complex formation in the system M2+-Nta3−-En (M = Ni, Cu, Zn, or Cd) in aqueous solution

Heterotrimetallic Complexes [{Pt(RNH2)2(

Heterotrimetallic Complexes [{Pt(RNH2)2(μ-NHCOtBu)2}2M](ClO4)n (M = Mn, Co, Cu, Ni, Cd, and Zn, n = 2; M = In, n = 3), [{Pt(NH3)(μ-DACHCOtBu)(μ-NHCOtBu)}2Ni](ClO4)2, and [{Pt(RNH2)2(NHCOtBu)2}3Ag3](ClO4)3 Bridged by Amidate Ligands: A Novel Amidate−Amine Interligand Reaction During the Pt−Ni Bond Formation

✍ Wanzhi Chen; Fenghui Liu; Takuya Nishioka; Kazulo Matsumoto 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB

## Abstract The neutral square‐planar complexes [Pt(NH~2~CH~2~CH~2~OCH~3~)~2~(NHCO__t__Bu)~2~], [Pt(DACH)(NHCO__t__Bu)~2~] (DACH = __trans__‐1,2‐diaminocyclohexane), and [Pt(NH~2~CH~2~CH~2~NMe~2~)(NHCO__t__Bu)~2~] have been prepared by hydrolysis of the corresponding [Pt(RNH~2~)~2~(NC__t__Bu)~2~](C