Thermochemical properties of gas phase mixed clusters: Water and sulfur dioxide with Na+ and Cl−
✍ Scribed by B.L. Upschulte; F.J. Schelling; R.G. Keesee; A.W. Castleman Jr.
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 436 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Standard free energy, enthalpy, and entropy data ;ue presented for association reactions of tbc ntixed cluster systems: Na+W, O,, (SO&, and CI--WZQ,(SO& with n -c m ranging up to a value of four. Thermodynamic cycles show the self-consistency of the data, or alternately allow cdcuLtion of additional leg of the cycle_ These support previous work in this laboratory which suzested a charge dclocalization in the [Cl-SO?]-complex. Qualitative evidence is presenrcd to show cooperative, and hindered bonding effects in the mbed clusters. Volume 111. number 4.5 CHEhlICAL PHYSICS LETTERS