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Thermochemical properties of 1,2,4,5-tetramethylbenzene, pentamethylbenzene, and hexamethylbenzene

✍ Scribed by M Colomina; P Jiménez; M.V Roux; C Turrión


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
463 KB
Volume
21
Category
Article
ISSN
0021-9614

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The photo-oxidation of hexamethylbenzene
✍ C. J. M. van den Heuvel; A. Hofland; H. Steinberg; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 470 KB

## Abstract In a two step reaction, hexamethylbenzene consumes two molecules of singlet oxygen to form epidioxy hydroperoxide **3**. The first step involves a [4 + 2]‐cycloaddition, which is followed by an ene‐reaction. The structure of the intermediary endoperoxide **2** has been established spect