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Thermochemical characteristics of solvation of ions in mixtures of water with formamide, dimethylsulfoxide and hexamethylphosphoric triamide

✍ Scribed by V.N. Vandyshev; V.P. Korolyov; G.A. Krestov


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
676 KB
Volume
169
Category
Article
ISSN
0040-6031

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The coordination structure of the cobalt(I1) ion and its chloro complexes of low concentration (-20 mmol dme3) in hexamethylphosphoric triamide (HMPA) has been explored by laboratory EXAFS (extended X-ray absorption fine structure) modified for fluorescence detection. The cobalt(I1) ion is four-coor