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Thermo-oxidation of polypropylene in the presence of PbO

✍ Scribed by L. Matisová-Rychlá; J. Rychlý; M. Vavreková

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
567 KB
Volume
2
Category
Article
ISSN
0141-3910

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Thermo-oxidation of polypropylene in the
Thermo-oxidation of polypropylene in the presence of triphenylphosphonium cyclopentadienylide
✍ L. Matisová-Rychlá; J. Rychlý; P. Ambrovič; M. Vavreková; I. Paška 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Akstract--From measurements of weight losses of samples of isotactic polypropylene (IPP) with triphenylphosphonium cyciopentadienylide (TPCP) under various conditions and from the measurements of time courses of chemiluminescence, kinetic parameters of the process were determined. At concentrations

Chemiluminescence in thermo-oxidation of
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Abstraet--42hemiluminescence in thermo-oxidation of polypropylene was interpreted, noting its course with time at different temperatures and the corresponding spectra. The light emission was attributed to decomposition of ~t-ketone-hydroperoxides and to chain oxidation of polymer proceeding via seco