## Abstract We discuss and demonstrate the potential of HSQC‐TOCSY and HSQC‐NOESY experiments to offer solutions for overlap problems in COSY and NOESY spectra, leading to improved signals that can be unambiguously assigned to individual carbons. Direct comparison of experimental ^1^H and ^13^C che
Thermo-hydro-chemical modelling of a porous medium submitted to high temperature: An application to an axisymmetrical structure
✍ Scribed by A Feraille-Fresnet; P Tamagny; A Ehrlacher; J Sercombe
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 647 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0895-7177
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✦ Synopsis
The problem of porous media submitted to high temperature is of high interest. In this paper, we propose to approach the phenomena taking place in a heated medium using the nonsaturated reactive porous media theory. We describe the material microstructure with a porosymmetric curve taking into account the effects of dehydration put in evidence by experimental studies. This paper focuses on an application of a simplified version of the model to an axisymmetrical structure under thermal load. A quasi-analytical model under simplified hypothesis is established. The various steps of calculation are detailed. Results of finite volumes calculi are then presented, showing the fields evolution.
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