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Thermische Zerfallsreaktionen von Nitroverbindungen in Stosswellen. II: Dissoziation von Nitroäthan

✍ Scribed by Klaus Glänzer; Jürgen Troe

Publisher
John Wiley and Sons
Year
1973
Tongue
German
Weight
563 KB
Volume
56
Category
Article
ISSN
0018-019X

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## Abstract The pyrolysis of 1‐ and 2‐nitropropane highly diluted in Ar has been studied in shock waves at temperatures K 915 < T < 1200 K and total gas concentrations 7 · 10^−6^ mol cm^−3^ < [Ar] < 1.5 · 10^−4^ mol cm^−3^. The reactions behind the shock waves have been followed by recording light

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The thermal dccornposition of CH,NO, highly dilutcd in Ar has been studicd in shock waves a t 900 < T < 1500 K and 1.5. mol/cm3. Concentration profiles of CH,NO, and NO, were rccordcd. The unimolecular rcaction was found to be in its falloff range. Limiting low pressure rate constants of k, = [Ar] .