**Thermal Rearrangement of 2‐Oxa‐bicyclo [3.3.1]‐non‐7‐en‐3‐ones; a Novel Lactone Rearrangement** Lactone (+)‐**2** was prepared by iodolactonisation and subsequent elimination in 51% yield from the known acid (+)‐**1** (__Scheme 1__). Alkylation of (+)‐**2** furnished (+)‐**3a**, (+)‐**3b** and (+
Thermische Umlagerung von (trans-2,3-Diphenylcyclopropyl)-dipyrrolidino-methan. vorläufige Mitteilung
✍ Scribed by Martin K. Huber; André S. Dreiding
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- German
- Weight
- 194 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Thermal rearrangement of (trans‐2,3‐diphenylcyclopropyl)‐dipyrrolidino‐methane under different conditions leads to mixtures which, after mildly acid work up, yield 2‐benzylidene‐1‐pyrrolidino‐indane (3) and 2‐benzyl‐indan‐1‐one (4) in strongly varying proportions. Under one of these conditions 4 is obtained from 3.
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