𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermische Umlagerung von (trans-2,3-Diphenylcyclopropyl)-dipyrrolidino-methan. vorläufige Mitteilung

✍ Scribed by Martin K. Huber; André S. Dreiding


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
194 KB
Volume
57
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Thermal rearrangement of (trans‐2,3‐diphenylcyclopropyl)‐dipyrrolidino‐methane under different conditions leads to mixtures which, after mildly acid work up, yield 2‐benzylidene‐1‐pyrrolidino‐indane (3) and 2‐benzyl‐indan‐1‐one (4) in strongly varying proportions. Under one of these conditions 4 is obtained from 3.


📜 SIMILAR VOLUMES


Thermische Umlagerung von 2-Oxa-bicyclo
✍ György Fráter 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 145 KB 👁 1 views

**Thermal Rearrangement of 2‐Oxa‐bicyclo [3.3.1]‐non‐7‐en‐3‐ones; a Novel Lactone Rearrangement** Lactone (+)‐**2** was prepared by iodolactonisation and subsequent elimination in 51% yield from the known acid (+)‐**1** (__Scheme 1__). Alkylation of (+)‐**2** furnished (+)‐**3a**, (+)‐**3b** and (+

Zur Photodimerisierung von 3-Phenyl-2H-a
✍ N. Gakis; M. Märky; H.-J. Hansen; H. Schmid 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 German ⚖ 305 KB

## Abstract Irradiation of 3‐phenyl‐2__H__‐azirine (**2**) in benzene solution with a high‐pressure mercury lamp yields 4,5‐diphenyl‐1,3‐diazabicyclo[3,1,0]hex‐3‐ene (**4**) and not 3‐phenylimino‐4‐phenyl‐1‐azabicyclo[2,1,0]pentane (**1**), as had been reported previously by others [2]. 2‐Methyl‐3‐

Reaktion von 3-Amino-2H-azirinen mit Dip
✍ Stanislav Chaloupka; Heinz Heimgartner 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 201 KB 👁 1 views

**Reaction of 3‐Amino‐2__H__‐azirines with Diphenylcyclopropenethione** 3‐Dimethylamino‐2__H__‐azirines (**4a**, **4b**) react with diphenylcyclopropenethione (**8**) to give 4(3 __H__)‐pyridinethione derivatives of type **10** __(Scheme 3)__. The reaction mechanism for the formation of **10** is g

Thermisch und photochemisch induzierte i
✍ Hansruedi Meier 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 206 KB 👁 1 views

**Thermal and Photochemically Induced Interamolecular 1,3‐Dipolar Cycloaddition Reactions of 5‐(2‐Allyloxyphenyl)‐2‐phenyltetrazole** The title compound **5** is easily obtained by a recently described procedure (__Scheme 2__). The tetrazole **5** reacts at 165–170° or on irradiation at room temper

Silberioneninduzierte Reaktion von 3-Chl
✍ Rudolf Schmid; Hans Schmid 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 256 KB 👁 1 views

## Abstract 3‐Chloro‐2‐pyrrolidinocyclohexene (**3**) in the presence of silver tetrafluoroborate in methylene chloride at −60° underwent cycloadditions with various 1,3‐dienes; the resulting iminium tetrafluoroborate salts **4a–8a** were hydrolysed to give the bicyclic and tricyclic ketones **4b–8