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Thermally Induced Skeletal Rearrangements of Tropilidenes 1

✍ Scribed by Berson, Jerome A.; Willcott, M. Robert

Book ID
118033076
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
1019 KB
Volume
88
Category
Article
ISSN
0002-7863

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✍ Werner Bernhard; Paul Brügger; Peter Schönholzer; Roland H. Weber; Hans-Jürgen H 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 630 KB

## Abstract It is shown that dimethyl 5, 6, 8, 10‐tetramethyl‐ (**3**) and 8‐ (__tert__‐butyl)‐5,6,10‐trimethylheptalene‐1, 2‐dicarboxylate (**5**), and their derivatives rearrange reversibly on irradiation or on heating to yield the corresponding 1,6,8,10‐tetramethyl‐ (**4**) and 8‐(__tert__‐butyl