Thermalization of fast nitrogen atoms in elastic and inelastic collisions with molecules of atmospheric gases
โ Scribed by V. Kharchenko; N. Balakrishnan; A. Dalgarno
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 1012 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1364-6826
No coin nor oath required. For personal study only.
โฆ Synopsis
The energy relaxation of fast nitrogen atoms due to elastic and inelastic collisions with molecules in the atmosphere is studied. A new formula for the energy relaxation kernel in the Boltzmann kinetic equation, which applies equally to elastic and inelastic collisions, is derived. Angular and energy dependent differential cross sections are used in calculations of the energy transfer rate. The energy relaxation kernel is evaluated for inelastic N+ N2 collisions with numerically determined differential cross sections for rotational and vibrational excitation of the N, molecules. The mean rate of energy loss, the average energy transfer per collision and mean thermalization times are calculated as functions of the kinetic energy of the nitrogen atoms. The contributions of elastic and inelastic scattering to the thermalization of N atoms in the terrestrial atmosphere are analyzed. The energy distribution functions of the fast nitrogen atoms are evaluated for thermospheric conditions. They depart significantly from a Maxwellian distribution at high energies.
๐ SIMILAR VOLUMES
Studies of internal energy changes between the partners in ion-molecule collisions can be facilitated by highresolution translational energy spectroscopy. Collisions of keV H', N + and 0' on molecular nitrogen and oxygen have shown that for 30 reaction channels all are consistent with spin conservat
Individual state-?-to-state rotational transitions have been resolved in small angle scattering of po!arized CsF molecules on Ne, Ar, Cz Hg. Nz. CO, COz. CHFS at center of mass energies of about 0.1 eV. The absolute inelastic cross sections range from 5 A up to 600 A2 \_ Most cf our knowledge oi ine