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Thermal valence isomerizations: stereochemistry of the 2,4,6-octatriene to 5,6-dimethyl-1,3-cyclohexadiene ring closure

✍ Scribed by Elliot N. Marvell; Gerald Caple; Bruce Schatz

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
221 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis

Thermal valence isomerization of conjugated trienes having a central cis double bond to give cyclohexadienes is a well established reaction (1). Most of the known examples involve medium ring trienes, and few pro-

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