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Thermal transformations of 1,3-pentadiene

โœ Scribed by N. I. Shuikin; S. S. Novikov; T. I. Naryshkina


Book ID
112490998
Publisher
Springer
Year
1954
Tongue
English
Weight
319 KB
Volume
3
Category
Article
ISSN
1573-9171

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Copolymerizations of 1,3-pentadiene (PD) with 1,3-cyclopentadiene (CPD) initiated by aluminium trichloride were carried out in toluene. The addition of CPD in the PD polymerization system does not affect the molecular weight but greatly increases the softening point of the polymer due to the introdu

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## R~Le pentadi~ne-l,3 peut ~tre polym~s6, en solution dam le benz~ne, en pr~nce d'un catalyseur associant le tri6thylaluminium et l'orthotitanate de n-butyle. A partir d'un diane chimiquemerit pur (99,9 pour cent), on obtient un polym~re dont une fraction importante est caract6ris~e par une crist