Thermal rearrangements of some 1,3-methanoindans (benzobicyclo[2.1.1]hexenes)
โ Scribed by Tanida, Hiroshi; Hata, Yoshiteru
- Book ID
- 126177169
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 409 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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Irradiation of 1-(o-tolyl)-3,4-benzobicyclo[3.1.0]hexenones (1) in benzene at 365 nm has resulted in clean conversion to 3-(o-tolyl)-1-naphthols (2) via 3-(o-tolyl)-1(2H)-naphthalenones. The reaction is suggested to occur mainly from (n, p\*) 3 state with a reaction rate higher than 10 10 s -1 .