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Thermal rearrangement of syn-7-(1,2-butadienyl)bicyclo[2.2.1]hept-2-ene - evidence of concertedness

✍ Scribed by Duncan, James A.; Lee, Bruce A.; Teng, David


Book ID
127303231
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
423 KB
Volume
48
Category
Article
ISSN
0022-3263

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Rearrangement of a Bicyclo[3.2.0]hept-2-
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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond