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Thermal rearrangement of enantioenriched α-hydroxy imines -II. Formal synthesis of (−)-perhydrohistrionicotoxin

✍ Scribed by Philippe Compain; Jacques Goré; Jean-Michel Vatèle


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
101 KB
Volume
36
Category
Article
ISSN
0040-4039

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Thermal rearrangement of cyclopropyl imi
✍ R.V. Stevens; Mark P. Wentland 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 121 KB

We recently reported (3) the total synthesis of the simple pyridine alkaloids myosmine [3] and apoferrorosamine [4] by means of the thermally induced, acid catalyzed, rearrangement of cyclopropyl ketimines [l]. The success and efficiency of these experiments has prompted us to further investigate th