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Thermal rearrangement of dienolesters. Sequential [1.3] sigmatropic rearrangement and intramolecular diels-alder cycloaddition of 1-methylene-2-methyl-2-propenyl hex-5-enoate

✍ Scribed by K.J. Shea; E. Wada


Book ID
104220647
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
201 KB
Volume
23
Category
Article
ISSN
0040-4039

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Cycloaddition Behavior of 2-Substituted
✍ Adam, Waldemar ;Pasquato, Lucia ;Will, Bernd ;Lucchi, Ottorino De πŸ“‚ Article πŸ“… 1987 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 562 KB

The reaction of PTAD with 2-trimethylsilyl-, 2-chloro-, 2-cyano-, and 2-methoxycarbonylnorbornadienes 1 ad, respectively, was investigated. In all cases homo Diels-Alder adducts were obtained, for 1 a the unexpected regioisomer, the 1-trimethylsilyl derivative 2a, and for other norbornadienes 1 b-d