𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermal rearrangement of anti-9-methyl-cis-bicyclo[6.1.0]nonatriene and syn-9-methyl-cis-bicyclo[6.1.0]nonatriene

✍ Scribed by Radlick, Phillip; Fenical, William

Book ID
127372314
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
359 KB
Volume
91
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Synthesis of anti-9-Bromo- and anti-9-Ch
Synthesis of anti-9-Bromo- and anti-9-Chlorobicyclo[4.2.1]nonatriene via Bicyclo[4.2.1]nonatriene→Bicyclo[4.2.1]nonatriene Rearrangement
✍ Melvin J. Goldstein; James P. Barren πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 German βš– 458 KB

The first syntheses of 9-bromo-and 9-chlorobicyclo[4.2.l]nona-2,4,6-trienes were each achieved in three stereoselective steps from the 9,9-bis(selenophenyl) derivative 9 in 79% overall yield for the bromide and 64% for the chloride. A deuterium-labeling experiment reveals the first rearrangement of