Thermal reaction of chromium (acyloxy) carbene complexes: synthesis of enol esters
β Scribed by Soderberg, Bjorn C.; Turbeville, Michael J.
- Book ID
- 127366299
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 381 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The carbanion generated from the methyl (pyrrolidino) chromium carbene complex 6a reacts with a variety of alkylating reagents to provide good to high yields of monoalkylated products. The alkylation reactions of the amino carbene complex were found to be significantly more efficient than alkoxy car
## Thermal Decomposition of Pentacarbonyl(1acyloxyalkylidene)chromium(0) Complexes: Formation of Z-Enol Esters. -A novel synthesis of enol esters in moderate to good yields by reaction of pentacarbonyl Cr(0) complexes (formed in situ from NMe + 4 chromate salts) with carboxylic acid halides is pr