Thermal properties of nematic main-chain polyesters with azoxybenzene mesogen
✍ Scribed by Y. Maeda
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 418 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0040-6031
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## Abstract The conformations of thermotropic polyesters with alternating mesogens and poly(methylene) spacers in the main chain were investigated by conformational calculations using the data of linear‐dichroism IR‐spectroscopy, X‐ray analysis and differential scanning calorimetry. The conformatio
## Abstract Melt polycondensation of a mixture of diethyl 5‐{6‐[4‐(4‐cyanophenylazo)phenoxy]‐hexyloxy}isophthalate and 4,4′‐bis(ethoxycarbonyl)azoxybenzene at various mole ratios with dihydroxyhexamethyleneoxy derivatives of diphenyls in the presence of zinc acetate afforded new combined‐type semi‐
## Abstract A “click” polymerization of dialkynes that contain an ester linkages and diazides to has been performed to synthesize various polyesters, termed “click polyesters” with a high $\overline M \_{\rm n}$ of 1.0 × 10^4^ to 7.0 × 10^4^ in an excellent yield. This polymerization accompanied a