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Thermal polymerizations of alkali 4-(1-bromoethyl)benzoates

✍ Scribed by Mari Inoki; Fumihiko Akutsu; Yasuyuki Kitayama; Koichi Shinoda; Yoshio Kasashima; Kiyoshi Naruchi

Book ID: 102490267
Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 351 KB
Volume: 17
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1996.030171108

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✦ Synopsis

Abstract

Thermal reactions of alkali salts of 4‐(1‐bromoethyl)benzoic acid in bulk were investigated. These reactions were found to produce unexpectedly the graft copolymer, poly(4‐vinylbenzoate)‐graft‐oligo(oxycarbonyl‐1,4‐phenylenethylidene) (1). The relative reactivity of the oligocondensation as well as the vinyl polymerization of the salts decreased in the following order: K > Na > Li. The reaction polymerization rate proceeded rapidly during the initial 15 min, and then slowed down.

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