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Thermal polymerization and photopolymerization of ethyl methacrylate with bis(cyclopentadienyl)titanium dichloride in a water–methanol mixture: Formation of a polymer with novel solubility characters

✍ Scribed by Tsuneyuki Sato; Taku Katayose; Makiko Seno


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
245 KB
Volume
79
Category
Article
ISSN
0021-8995

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✍ Tsuneyuki Sato; Tatsuo Umenoki; Makiko Seno 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB 👁 2 views

Methyl methacrylate (MMA) was observed to be easily polymerized in the photopolymerization with bis(cyclopentadienyl)titanium dichloride (Cp 2 TiCl 2 ) in a water-methanol mixture under irradiation of a 15-W fluorescent room lamp. The polymerization proceeded heterogeneously. The rate ( R p ) of het