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Thermal Isomerizations of cis , anti , cis -Tricyclo[7.4.0.0 2,8 ]tridec-10-ene

โœ Scribed by Leber, Phyllis A.; Mann, George R.; Hancock-Cerutti, William; Wipperman, Matthew F.; Zohrabian, Sylvia; Bell, Ryan M.; Baldwin, John E.

Book ID
126954849
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
606 KB
Volume
77
Category
Article
ISSN
0022-3263

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Kinetics of the thermal isomerization of
Kinetics of the thermal isomerization of cis, anti, cis-tricyclo[3.1.0.02,4]hexane
โœ John E. Baldwin; James Ollerenshaw ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 156 KB

The cls,anti,cis isomer of tricyclo[3.1.0.0 2'4]hexane,2-5 first secured by Allred and Hlnshaw in 1968, may be obtained directly in 85% conversion through reaction of a solution of bicyclo[2.l.O]pent-2-ene6 in tetrahydrofuran with diazomethane in the presence of powdered cuprous chloride.