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Thermal isomerizations of 2-methylenebicyclo[2.1.0]pentane

โœ Scribed by Andrews, Gerald D.; Baldwin, John E.


Book ID
127079943
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
459 KB
Volume
53
Category
Article
ISSN
0022-3263

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Thermal unimolecular isomerization of 1,
โœ R. Srinivasan ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 593 KB

The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =