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Thermal isomerization of 1-morpholino-3-phenyl (or vinyl)-allenes: synthesis of the [1,4]oxazino-[4,3-a]azepine framework

✍ Scribed by Theo Mayer; Gerhard Maas


Book ID
103403853
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
238 KB
Volume
33
Category
Article
ISSN
0040-4039

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## Abstract Reaction of thiosemicarbazides (III) with Me‐I/AcONa gives regioselectively the linearly fused products (IV) while reaction of compounds (III) with DCC gives predominantly the angularly fused products (VI).