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Thermal instability of 1- and 2-norbornyl and of 1-bicyclo[2.2.2]octyl radicals in a mass spectrometer

✍ Scribed by McAllister, T.; Dolesek, Z.; Lossing, Frederick P.; Gleiter, Rolf.; Schleyer, Paul v. R.

Book ID: 126463380
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 301 KB
Volume: 89
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00999a063

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## Abstract 4‐Substituted bicyclo [2.2.2] oct‐1‐yl radicals were generated by bromine atom abstraction from the corresponding 1‐bromobicyclo [2.2.2] octanes and observed in solution by EPR spectroscopy. A tendency towards lower __a__(H~β~) and __a__(H~γ~) values for inductively electron‐withdrawing